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The service that enhances the workflow by integrating with automated UI testing is App Center Test. This service facilitates the execution of automated tests on real devices hosted in the cloud, allowing developers to ensure their applications function as expected across a variety of environments and device configurations. By automating this testing process, App Center Test allows teams to identify issues earlier in the development cycle and ensures a smoother deployment process.

In terms of the other services, App Center Build is aimed at automating the app building process to streamline continuous integration and continuous deployment practices. App Center Distribute handles the distribution of built apps to testers and users, providing an effective way to manage pre-release testing. App Center Monitor focuses on tracking and analyzing app performance and understanding user engagement, which is vital for optimizing applications but does not specifically relate to automated UI testing. Thus, App Center Test is the clear choice for integrating automated UI testing within the workflow.