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When a team practices Scrum, the appropriate work item process to use is Scrum. Scrum is a specific framework within Agile methodologies that emphasizes iterative development, sprints, and defined roles such as Scrum Master and Product Owner. By employing the Scrum work item process, teams can effectively manage their product backlogs, sprints, and workflows in a manner that aligns closely with Scrum principles. This ensures that the practices, ceremonies (like daily stand-ups and sprint reviews), and artifacts (such as the product backlog and sprint backlog) are utilized effectively.

Using the Scrum work item process allows the team to adhere to the prescribed Scrum methodologies, facilitating better collaboration and delivery of increments of working software. This focuses on continuous improvement and engagement with stakeholders, which are key aspects of the Scrum framework.

On the other hand, the Agile process represents a broader category of methodologies that includes Scrum but does not provide the specific structure that Scrum does. CMMI (Capability Maturity Model Integration) is geared towards process improvement in organizations and is not a fit for teams specifically practicing Scrum. XP (Extreme Programming) focuses on software engineering practices and may not align closely with Scrum's iterative approach. Thus, Scrum as a work item process is the best fit for a team practicing Scrum.