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The most suitable application for global communication among development team members while integrating directly with Azure DevOps is Microsoft Teams. This application provides a comprehensive platform for collaboration, featuring chat, video conferencing, file sharing, and integration with various services, including Azure DevOps.

Microsoft Teams enables team members to communicate effectively in real-time, share updates, and collaborate on projects regardless of their geographic location. The integration with Azure DevOps allows users to receive notifications about their projects, access work items, and carry out many DevOps-related activities directly from the Teams interface. This streamlines communication and enhances team productivity by keeping all stakeholders engaged and informed within a single platform.

Other options, such as Microsoft Project or Bamboo, do not focus primarily on real-time communication and collaboration. Microsoft Lync, while designed for communication, has been largely replaced by Microsoft Teams and does not have the same level of integration with Azure DevOps. Therefore, the functionality, collaboration features, and seamless integration capabilities of Microsoft Teams make it the optimal choice for global communication in a DevOps context.