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The compatibility of source control systems with App Center Build focuses on integration capabilities that allow developers to automate the build process for their applications.

GitHub, Bitbucket, and Azure DevOps are all popular source control systems that provide robust APIs and hooks for integration with build systems. App Center Build supports these platforms, enabling seamless connection for continuous integration and continuous deployment (CI/CD) workflows. This means that when developers push code to repositories on these platforms, App Center can automatically trigger builds, allowing for efficient implementation of development cycles.

In contrast, while Git and Mercurial are forms of version control in their own right, the broader support and features that come with the integration of GitHub, Bitbucket, and Azure DevOps with App Center are more comprehensive and advantageous for modern development practices.

Subversion and CVS are older version control systems that may not have the same level of integration support as the others listed in the correct answer. Only Azure DevOps as a compatible source control system does not encompass the wider range of options available in App Center, which is enhanced by support for multiple platforms. Thus, the inclusion of GitHub and Bitbucket alongside Azure DevOps provides developers with flexibility and choice in structuring their development workflows.